Wednesday, August 26, 2015

Substitution derivatives of carboxylic acids

Derived by substituting one or more hydrogen atoms with another atom or functional group
They have properties similar to carboxylic acid

Halogenoacids
Mostly crystalline and toxic
The closer is a halogen atom to the carboxyl group, the acid is stronger
The higher the number of halogen atoms in the molecule, the acid is stronger

Hydroxy acids
Crystalline
They are prepared by hydrolysis of the sodium salts of halogen acids

Salicylic acid
Salicylic acid
It is used in dermatology - low concentration stimulates the skin epithelium growth

Lactic acid
Is created by lactic fermentation of sugars
In milk, cheese, sauerkraut

Citric acid
In fruits
Part of the Krebs cycle - Intermediate of metabolism of nutrients
Lactic acid

Tartaric acid
In fruits
It is used to adjust the acidity of wine, fruit beverages

Ketoacids
Participate in the biochemical processes

Pyruvic acid
It is a product of glycolysis
It is metabolism of alcohol and lactic fermentation
Pyruvic acid

Amino acids
COOH - sour
NH2 - alkaline
Colorless, crystalline

Isoelectric point - the pH at which the amino acid is neutral

Dipeptide
Molecule composed of two molecules of the amino acid
If both are the same amino acid = homodipeptid
If the amino acids are different = heteropeptid

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